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Showing 1 to 3 of 3 for “"double bond cleavage"”.

  1. Oxygen Atom Transfer Reactions Catalyzed by Molybdenum and Tungsten Oxo Transferase Mimics

    … epoxides, the reaction led to carbon-carbon double bond cleavage in aryl-substituted alkenes. Computational studies suggest that O₂ transfer from a molybdenum oxo/peroxo intermediate facilitates the formation of 1,2-dioxetane species, which subsequently decompose into benzophenone and …

    uic

  2. Frustrated Lewis Pair Reactivity of Phosphino-Phosphenium Cations

    … the century-old paradigm that activation and cleavage of small molecules such as H2 belonged to the realm of transition metal chemistry. Since Stephan and co-workers’ seminal report on reversible H2 activation using a main-group phosphinoborane, the field of FLPs has grown immensely to show …

    toronto-retro Repository record for Frustrated Lewis Pair Reactivity of Phosphino-Phosphenium Cations (opens in a new tab)

  3. Nitrate Radical-Mediated Oxidative Cleavage of Olefins Using TiO2 Photocatalysis

    … stems from their reactive carbon-carbon double bonds, which facilitate numerous chemical transformations. Among these, oxidative cleavage has emerged as a critical process, enabling the conversion of olefins into high-value carbonyl compounds such as aldehydes and ketones. These compounds …

    trento Repository record for Nitrate Radical-Mediated Oxidative Cleavage of Olefins Using TiO2 Photocatalysis (opens in a new tab)