Global ETD Search

Late transition metal bimetallics for photocatalytic hydrogen production, M-X and C-H bond activation

Esswein, Arthur JMassachusetts Institute of Technology2007

… elements employed have focused on bimetallic complexes of late transition metals that exhibit an unusual two-electron mixed valence ground state. Initial studies focused on the mechanistic elucidation of the reported photocatalytic production of hydrogen from homogeneous hydrohalic acid …

mit Repository record for Late transition metal bimetallics for photocatalytic hydrogen production, M-X and C-H bond activation (opens in a new tab)

Development of Ion Pairing Strategies that Utilise Cations to Control Selectivity in Transition Metal-Catalysed Functionalisation of C–H Bonds

Williams, BenjaminUniversity of Cambridge2021

… through ion pairing to a negatively charged dirhodium complex. This thesis highlights the generality of ion pairing strategies towards addressing selectivity challenges in transition metal-catalysed functionalisations of C–H bonds. It is hoped that the results presented herein will stimulate …

cambridge Repository record for Development of Ion Pairing Strategies that Utilise Cations to Control Selectivity in Transition Metal-Catalysed Functionalisation of C–H Bonds (opens in a new tab)

Dirhodium(II,II) paddlewheel complexes conjugated to a polypyridyl tris-amine scaffold: synthesis and application as asdjncaslpre-catalysts in the hydroformylation of 1-octene

de Doncker, StephenDepartment of Chemistry2020

… increasing the activity through multinuclearity. Dirhodium(II,II) complexes contain two rhodium atoms, a metal-metal bond and an oxidation state of 4+ over the bimetallic core, resulting in each rhodium atom having an oxidation state of 2+. The electronic and steric influences can be altered by …

cape-town Repository record for Dirhodium(II,II) paddlewheel complexes conjugated to a polypyridyl tris-amine scaffold: synthesis and application as asdjncaslpre-catalysts in the hydroformylation of 1-octene (opens in a new tab)

Studies on Chemo- and Site-Selective C-H Amination of Aniline and Phenol Derivatives with Dirhodium Catalysts and Catalytic Asymmetric Synthesis of Inherently Chiral Calixarenes

Chen, GongKyoto University2021

kyoto Repository record for Studies on Chemo- and Site-Selective C-H Amination of Aniline and Phenol Derivatives with Dirhodium Catalysts and Catalytic Asymmetric Synthesis of Inherently Chiral Calixarenes (opens in a new tab)