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Showing 1 to 2 of 2 for “"diazo ester"”.
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Applications of C₂-symmetric bis(azaferrocenes) in asymmetric copper-catalyzed reactions
… is particularly effective, and using a hindered diazo ester, an array of monosubstituted olefins has been cyclopropanated with excellent diastereo- as welf as enantioselectivity. The level of stereoselection achieved is comparable to some of the best ligands reported to date. Preliminary studies …
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Exploring the reactivity of alpha-triorganylsilyl alpha-diazo esters : C-H activation, insertion reactions, and rearrangements
… reactions of Alpha-triorganylsilyl Alpha-diazo esters have been studied, with an emphasis on: · Dirhodium(II)-catalyzed insertions of Alpha-triorganylsilyl Alpha-diazo esters into activated C-H bonds. · Dirhodium(II)-catalyzed reactions of -triorganylsilyl Alpha-diazo esters with various …