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Showing 1 to 1 of 1 for “"diastereotopic group selective lactonization"”.
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Synthesis and function of the conserved motif of mycosamine-containing polyene macrolides
… acid and the rare aminosugar mycosamine. These groups are proposed to form polar interactions which stabilize the putative ion channel complex, anchor these compounds to the lipid bilayer, and/or promote an interaction with sterol. We employed a series of AmB derivatives lacking each of these …