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Showing 1 to 4 of 4 for “"desilylation"”.
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Producing Enantiopure Secondary Alcohols via a Silylation based Kinetic Resolution and a One-Pot Polishing Sequence
… through kinetic resolutions via silylation and desilylation. Chapter 2 highlights how we have combined a moderately selective asymmetric reaction (either a reduction or allylation) with a kinetic resolution (via acylation or silylation) to generate enantiopure compounds (enantiomeric excess (ee) …
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Efforts Toward the Total Synthesis of Asparagamine A
… sequential vinylogous amide O-sulfonylation and desilylation. Several strategies designed to construct the fully oxygenated aza-tricyclo[5.3.0.0 4,8]decane core are also presented.
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Studies on the use of alpha-silyl substituted carbanions in organic synthesis
… reactions on alkylation, protonation or desilylation. Further, on reacting with nucleophiles such as hydrogen halides and trimethylsilyl reagents, ring-opened products are formed. The silylaziridines react analogously to silyl epoxides with hydrogen halides; these involve an Sy2 mechanism …
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Gas transport properties of reverse selective nanocomposite materials
… with adventitious water to form brucite. A desilylation reaction occurred when brucite was exposed to polymers or small molecule compounds that contained a trimethylsilyl group attached to a conjugated organic backbone. This reaction caused certain disubstituted polyacetylenes to become …