Global ETD Search
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Showing 1 to 2 of 2 for “"dearomative dihydroxylation"”.
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Total synthesis of lycoricidine via photochemical dearomative dihydroxylation
… of lycoricidine utilizing a photochemical dearomative dihydroxylation of bromobenzene. Modified Narasaka-Sharpless dihydroxylation generates a product bearing both the electrophile and nucleophile for an unprecedented transpositive Suzuki coupling. Hetero-Diels-Alder cycloaddition is used …
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Dearomative transformations in synthesis: I. Dearomative dihydroxylation with arenophiles II. Total synthesis of lycoricidine and narciclasine III. Towards the total synthesis of collybolide
… particular, there is a paucity of reactions for dearomative installation of functionality into simple arenes in a selective and mild fashion. The first chapter of this dissertation describes the development of a dearomative functionalization reaction developed by our laboratory for the regio- and …