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Showing 1 to 3 of 3 for “"cyanide-bridged"”.
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Cyanide-bridged polynuclear complexes
The three mixed valent dinuclear cyanide-bridged complexes LMCNFeCl3, (LM = Cp(dppe)Fe, Cp(dppe)Ru and Cp(PPh3)2Ru) were synthesized and characterized by X-ray single crystal determination, IR, UV-Vis and cyclic voltammograms, respectively. The three mixed valent dinuclear complexes display metal- …
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Reactions at coordinated ligands: redox-active ligands and coordination of Lewis acids
… explored here in. The coordination of boranes to cyanide ligands is well know, however, this theme has not been applied to hydrogenase models. Cyanide is an essential component of the [FeFe]- and [NiFe]-hydrogenase active sites, both enzymes feature two cyanide ligands, however, models using …