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Showing 1 to 20 of 40 for “"crystal chemistry"”.
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The crystal chemistry of titanite
The chemical substitutions of primary importance in natural titanites are (Al,Fe)<sup>3+</sup> + (F,OH)<sup>-</sup> ⇆ T<sub>1</sub><sup>4+</sup> + O<sup>2-</sup> , where total Al + Fe is not greater than 30 mol % and Al is usually predominant. Electron microprobe analyses and bond strength …
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The crystal chemistry of tetrahedrite
… so, whereas Ag:Cu substitution is not. The crystal chemistry of tetrahedrite can be rationalized by considering the structure to be generally analogous to sodalite, i.e., a framework of comer-connected M(l)Y4 tetrahedra containing an ZM(2)₆ octahedron rather than an interframework cation or …
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The crystal chemistry of staurolite
… relationships are explained on the basis of the crystal structure and site occupancies. Natural specimens have uniformly shorter a cell edges {by ~0.015Å) than synthetic Fe-Mg staurolites. Improved curves showing the relationship of 2V and refractive indices to Fe-content have been established.
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Crystal chemistry of ferric-rich fayalites
Thesis (Ph.D.)--Massachusetts Institute of Technology, Dept. of Earth and Planetary Sciences, 1983.
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Crystal chemistry of the humite minerals
… amounts of other mineral impurities. Single crystal x-ray diffraction studies were made on nine microprobe analyzed humites to determine the effects of minor chemical substitution on the unit cell parameters. These studies show that the substitution of (Fe + Mn) for Mg increases the …
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Mössbauer spectroscopy and crystal chemistry of aenigmatites
Thesis (M.S.)--Massachusetts Institute of Technology, Dept. of Earth and Planetary Sciences, 1983.
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Synthesis and crystal chemistry of lanthanide allanites
Metamictization and complex chemistry are major obstacles to the crystal chemical characterization of natural allanites. To overcome these problems, allanites, Ca(REE)Fe²+Al₂Si₃O₁₂(OH), where REE = La, La-Ce, Ce, Nd, Sm, Eu, Gd, Er, Dy, Yb and Y have been synthesized hydrothermally from unbuffered …
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Structures and crystal chemistry of wollastonite and pectolite
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Geology and Geophysics, 1962.
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The structures and crystal chemistry of bustamite and rhodonite
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Geology, 1962.
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The structures and crystal chemistry of the aluminum-silicate minerals
Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Geology and Geophysics, 1961.
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Mössbauer spectroscopy and crystal chemistry of natural Fe-Ti garnets.
Thesis. 1977. M.S.--Massachusetts Institute of Technology. Dept. of Earth and Planetary Sciences.
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(Na,K) Aluminosilicate Hollandites: Structures, Crystal Chemistry, and High-pressure Behaviour
… the c axis. Structural refinements of single-crystal data collected for KAlSi3O8 and K0.8Na0.2AlSi3O8 hollandites are consistent with Si and Al disorder among the octahedral sites. The major difference between the KAlSi3O8 hollandite end-member and the K0.8Na0.2AlSi3O8 sample is the presence …
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New Developments in the Crystal Chemistry of Selected Borophosphates and Phosphates
… contributions to borophosphate structural chemistry. The mild hydrothermal method was employed for the syntheses. During the investigation of borophosphates containing alkali–metals and scandium, the following three compounds were prepared and structurally characterized: MISc[BP2O8(OH)] (MI …
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High temperature crystal chemistry of hydrous Mg- and Fe-rich cordierites
Structural refinements have been completed using data recorded for a Mg-rich cordierite at 24°C, 375°C, 775°C and 24°C (after heating to 775°C) and for an Fe-rich cordierite at 24°C and 375°C. The mean T-0 bond lengths in both cordierites remain unchanged but the mean octahedral bonds (M-0) …
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Some Aspects of the Crystal Chemistry of Perovskites under High Pressures
This thesis makes contributions to the methodology of quantitative description of the tilting systems of perovskite structures and theoretical analysis of high-pressure phase transitions of representative perovskites. Chapter 1 and 2 introduce the perovskite structures, tilting classification and …
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Navigating the Intermetallic Landscape: From Quasicrystal Approximants to High Pressure Crystal Chemistry
… inorganic solids. Here, we explored the complex crystal chemistry enabled by incorporating Au in the presence of electropositive (rare earth and alkali metals) and main group element systems revealing a series of compounds including Zintl-like structures, Frank-Kasper phases, interstitial …
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