Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 3 of 3 for “"cross-electrophile coupling"”.
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Reductive Alkylation Reactions Using Tetramethyldisiloxane and Potassium Tert-Butoxide Via Reductive-Radical Polar Crossover
… of vinylarenes (chapter 2), and the cross-electrophile coupling of alkyl halides (chapter 3). This simple system of commonly available reagents is suspected to form a hypercoordinate silicon complex capable of acting as a single-electron donor as well as a hydrogen-atom donor. In each …
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Catalysis, Synthesis, and Materials in Support of Chemical Understanding and Global Health
… are synthesized using a nickel-catalyzed cross-coupling reaction between allyl trifluoroacetates and vinyl bromides. The utility of this cross-electrophile coupling is showcased in part by the synthesis of the RST fragment of the marine ladder polyether, maitotoxin. Construction of this …
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Coordination chemistry of unusual oxidation states of nickel and palladium relevant to homogeneous catalysis
… important areas including, but not limited to, cross-coupling catalysis, C-H activation, olefin polymerization, and cross-electrophile coupling. In addition, several metalloenzymes found in Nature that catalyze important small-molecule activation processes feature Ni at their active site. The …