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Showing 1 to 3 of 3 for “"coordination polymerization"”.
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Synthesis and characterization of terpyridine-based fluorescent coordination polymers
… is the best suited metal ion for the reversible coordination of the terpyridine ligand. Thus, supramolecular coordination polymerization of perylene bisimide fluorophores containing terpyridine functionalities have been investigated by using Zn2+ as metal ion. The formation of the dimeric …
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Siloxane modified polyurea and polyurethane urea segmented copolymers
… <Mn>) prepared via aluminum porphorin initiated coordination polymerization. The resulting segmented copolymer showed much higher tensile strength and better thermal stability than polyureas based on commercial PPO which contains some terminal unsaturation. This was attributed to the achievement …
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Towards polyethylene-based materials with non-alternatively incorporated carbon monoxide monomer
… (polyketones) was pursued via insertion polymerization methods through palladium(II) and nickel(II) catalysis. Specifically, phosphine sulfonate palladium(II) precatalysts derived from the in situ complexation of palladium(II) acetate and phosphine sulfonate, were found to facilitate the …