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Showing 1 to 2 of 2 for “"convolution voltammetry"”.
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Reductive and oxidative dissociative electron transfers: transition between the concerted and stepwise mechanistic pathways
… both the direct electrochemical (linear sweep voltammetry and convolution voltammetry) and indirect electrochemical (homogeneous redox catalysis) reductions of the epoxyketones are presented. In cases where the ring-closed radical anion generated by reduction of the epoxyketones is resonance …
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Electrochemical oxidation of aliphatic carboxylates: Kinetics, thermodynamics, and evidence for a shift from a concerted to a stepwise mechanism in the presence of water
… has been investigated via conventional (cyclic voltammetry) and convolution voltammetry. The oxidation potential for tetra-n-butylammonium acetate was determined to be 0.60 ± 0.10 (vs. Ag/ (0.1 M) AgNO₃) in anhydrous acetonitrile. The results also indicated the mechanism of oxidation was …