Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 5 of 5 for “"cis-Decalin"”.
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“Trans-Positioning” Carbons within Strained Caged Bicyclic(s): ROM/RCM (Ring-Opening/Ring-Closing) Metathesis and Dieckmann/Retro-Dieckmann Condensation Routes to a Cis-Decalin Infrastructure
<p>This dissertation describes methodology work involving a “Trans-Positioning” motif engaging strategically positioned carbons within a strained bi-carbocyclic core and on a tethered free-dangling hydrocarbon chain ultimately for skeletal rearrangement. Trans-alkenylation and trans-acylation …
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Exploring Enantioselective and Multicomponent One-Pot Reactions Utilizing Alkynes as Linchpins Toward Biologically Active Molecules
… tandem DA reaction. From this tandem DA, a cis-decalin is produced. There are many biologically active terpenoids that contain the cis-decalin structural motif. This two-fold DA reaction proved to be a good method for rapid generation of cis-decalin molecules possessing biological activity. …
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DESIGN, SYNTHESIS, AND OPTIMIZATION OF SMALL-MOLECULE CD4 MIMETICS AS HIV-1 ENTRY INHIBITORS AND SYNTHETIC EFFORTS TOWARD THE TOTAL SYNTHESIS OF NAHUOIC ACID Cii
… preclinical advancement of lead compounds, a concise and scalable synthesis of the next-generation indoline CD4mc, CJF-III-288, was established. The revised route streamlined the overall sequence, minimized reliance on chromatographic purification, and enabled multigram production (>20 g) …
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Deuterium NMR relaxation studies of liquids in confined geometries
… liquids of cyclohexane-d$\sb{12}$ and cis-decalin-d$\sb{18}$ represent the weakly interacting liquids. In a first approximation, toluene-d$\sb1$ and dioxane-d$\sb8$ are chosen as examples of liquids with intermediate interactions with the silica surface. The experimental relaxation data …
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Transition Metal Heterogeneous Catalysis Towards Applications in Sustainable Energy: Leveraging Rational Design Principles for Activity, Stability, and Stereoselectivity
… catalysts in naphthalene and tetralin to decalin conversion rates per active site, however with a notable stereoselectivity toward cis-decalin across compared to the other Ni catalysts. This work highlights Ni-MHOFs as precursors for transition metal catalysts that emulate the …