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Showing 1 to 1 of 1 for “"chlorophosphines, Ge-P bond, germylenes, insertion, Sn-P bond, stannylenes"”.
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Formal Insertion Reactions Of Stannylenes And Germylenes Into Phosphorus-Halogen Bonds: A Structural And Mechanistic Investigation
<p>Insertion reactions of Group 14 carbenoids, divalent species of the form (R<sub>2</sub>N)<sub>2</sub>M (M = Ge or Sn) into the P-halogen bond of halophosphines have been known for some time. However, very few examples have been reported and no evidence has been presented regarding the mechanism …