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Towards Automation of Continuous Chemoenzymatic Syntheses of Plasticizers, Nitriles, and Chiral Esters from Renewable Resources

Adebar, NiklasUniversität Bielefeld

bielefeld Repository record for Towards Automation of Continuous Chemoenzymatic Syntheses of Plasticizers, Nitriles, and Chiral Esters from Renewable Resources (opens in a new tab)

Part I. Rhodium-catalyzed asymmetric functionalization of allylic amines Part II. Harnessing kinetic driving forces in alkyne metathesis for the synthesis of complex molecular architectures

Laffoon, Joshua DonnUniversity of Illinois at Urbana-Champaign2021

… functionalization of allylic amines to form chiral products such as β-branched amides and esters, and γ-branched amines. We developed a modular synthetic strategy that enables the diversification of a single allylic amine scaffold into many value-added products. Chiral, β-branched carbonyl …

uiuc Repository record for Part I. Rhodium-catalyzed asymmetric functionalization of allylic amines Part II. Harnessing kinetic driving forces in alkyne metathesis for the synthesis of complex molecular architectures (opens in a new tab)