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Showing 1 to 1 of 1 for “"chiral diamino alcohol"”.
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New frontiers in allylic C––H amination via palladium/sulfoxideoxazoline catalysis
… enables unprecedented access to anti-1,3 amino alcohols in good yields (33 substrates, avg. 66%) and high selectivities (avg. 10:1 dr). Switching ligand to (±)-CF3-SOX using a less bulky quinone oxidant (BQ), the kinetic syn- 1,3 amino alcohol motif can be accessed in comparable yields and …