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Showing 1 to 1 of 1 for “"chiral acetate"”.
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Investigations of metalloenzymes involved in bacterial natural product biosynthesis
… using SAM derived from methionine that was chirally labeled at the methyl position with deuterium and tritium were derivatized and analyzed, revealing overall retention of methyl stereochemistry during the reaction and therefore inversion during the radical methyl transfer step. The second …