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Showing 1 to 2 of 2 for “"chiral P,N-ligand"”.
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Ligand Dependent Regioselectivity in Palladium Mediated Allylic Alkylation
In this thesis, different aspects on ligand dependent regioselectivity in palladium mediated allylic alkylation have been studied. It is believed that the regioselectivity is a result of nucleophilic attack trans to phosphorous when applying ligands wih different donor atoms. The regioselective …
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Synthesis of chiral phosphino-sulfoximines through phospha-Michael addition and their evaluation as 1,5-P,N-Ligand in asymmetric allylic alkylation
… the availability of several classes of P,N-ligands, there is still a quest for this new type of ligands for many catalytic applications. This work describe the synthesis of new phosphino-sulfoximines and their application as 1,5-P,N-ligand in palladium-catalyzed asymmetric allylic …