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Showing 1 to 4 of 4 for “"catalytic hydroboration"”.
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Catalytic hydroboration: a study of model hydridoiridium and hydridorhodium boron complexes
The mechanism of catalytic hydroboration was studied through the use of iridium and rhodium model complexes. Oxidative addition of the B-H bond in (1,2-phenylenedioxy) borane (catecholborane) to (Me₃P)₃Ir(Cl)(H) (BO₂C₆H₄ (<B>II</B>) produces <i>mer</i>-(Me₃P}₃Ir(Cl)(H)(B0₂C₆H₄) (<B>II</B>), which …
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Segmented Aromatic Polymers Containing Thermally Reversible Linkages
… ring substituent, and from the utilization of catalytic hydroboration to improve atom-efficiency. We showed that hydroquinones with widely varying functionality can be prepared efficiently by our method; these findings were published in the journal Tetrahedron in 2018. The second stage (Chapter …
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Metal-catalyzed reactions.
… areas of interest were in the directed, catalytic hydroboration of olefins and in nucleophilecatalyzed reactions. Indenylrhodium(olefin)2 (and other Cp-derived rhodium complexes) were utilized in the directed hydroboration reactions. Both iron and ruthenium complexes with n-bound …