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Showing 1 to 2 of 2 for “"carbonyl ylides"”.
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Controlling and Exploiting Spiropyran-based Mechanochromism
… backbone</p><p>results in ring-opening to carbonyl ylides during sonication, whereas epoxides lacking</p><p>an adjacent alkene do not. Upon release, tension-trapped ylides preferentially close to</p><p>their trans-epoxides in accordance with the Woodward-Hoffman rules. The reactivity …
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Exploring the reactivity of alpha-triorganylsilyl alpha-diazo esters : C-H activation, insertion reactions, and rearrangements
… esters with various acyclic and cyclic carbonyl precursors. · The syntheses of Alpha-silyl-substituted Alpha-keto esters, their corresponding hydroxy esters and hydroxy acids, in addition to investigating dirhodium(II)-catalyzed O-H insertion reactions. Insertion of benzyl and ethyl …