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Showing 1 to 5 of 5 for “"carboamination"”.
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Total synthesis enabled by nickel-catalyzed transformations: Dearomative carboamination and methylenecyclopropane annulation
… a novel nickel-catalyzed asymmetric dearomative carboamination reaction. This strategy relies on the ability of N-methyl-1,2,4-triazoline-3,5-dione (MTAD) to undergo a [4+2] cycloaddition with benzene to form an intermediary cycloadduct that can then be subjected to a transition metal and …
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I. Palladium-catalyzed anti-Markovnikov oxidative amination of olefins II. Catalytic deracemization of axially chiral diols III. Three component carboamination of electron deficient alkenes
… we have developed a copper-catalyzed 3-component carboamination reaction. This transformation converts alkenes, aryl amines, and alkyl halides into densely functionalized lactams. The use of acrylate alkenes is a notable step forward in the area of radical carboamination, as previous work has …
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I. Development of three-component alkene carboamination reactions II. Palladium-catalyzed anti-Markovnikov oxidative amination of alkenes III. Chloroform as a carbon monoxide precursor: in or ex situ generation of co for pd-catalyzed carbonylations IV. Hydroalkylation of alkenes via photoredox catalysis
… three approaches for the three-component carboamination of alkenes. The first leverages the umpolung tactic, using electrophilic amines and nucleophilic carbon components. An uncatalyzed mechanism involving radical intermediates was elucidated. The reaction displays poor chemoselectivity …
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Development of three-component alkene and 1,3-diene carbofunctionalization reactions
… we have developed a three-component alkene carboamination reaction. This system offers access to complex amine products from simple starting materials and proceeds under mild reaction conditions. Critically, this transformation combines disconnected carbon, nitrogen, and alkene moieties as …
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Advances in synthetic methodology: Dearomative aminofunctionalization of arenes and high-throughput reaction discovery
Submission original under an indefinite embargo labeled 'Open Access'. The submission was exported from vireo on 2025-03-28 without embargo terms