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Showing 1 to 4 of 4 for “"carbinolamine"”.
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Study on the formation of nitrogenous disinfection by products from the reaction between dichloroacetaldehyde and monochloramine
… reacted quickly and reached equilibrium with carbinolamine 2,2-dichloro-1-(chloroamino)ethanol. Then, the carbinolamine underwent two parallel reactions where, (1) it slowly dehydrated to 1,1-dichloro-2-(chloroimino)ethane and further decomposed to dichloroacetonitrile and (2) it was oxidized …
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Formation of (halo)acetamides and (halo)acetonitriles from the reaction of monochloramine and (halo)acetaldehydes in water
… ozone and free chlorine disinfection, to form carbinolamines that slowly dehydrate to imines which undergo fast decomposition to nitriles. It is also known that nitriles can hydrolyze to its corresponding amides. However, in this study the formation rate of amides was found to be significantly …
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Preparation and reactions of some orthomanganated ketones, amides and aldehydes
… and is of interest as a rare example of a stable carbinolamine. Possible reaction pathways to the variety of product types are considered throughout. [Diagram] (56) Some preliminary studies into electrophilic substitutions of (arene)M(CO)₃ (M= Cr, Mn) complexes were conducted. Despite an apparent …
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Studies of catalysis of the hydrolysis of phenyl glycinate and some related esters
… concept of rate-determining decomposition of a carbinolamine species, which is also consistent with an observed small effect of temperature on the overall catalytic rate constant. (iii) Imidazole. Unlike the case for 4-nitrophenyl esters, the kinetics are dominated for both neutral and …