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Showing 1 to 3 of 3 for “"boron-"ate""”.
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Diastereoselective α-Alkylation of Chiral β-Borylated Esters
The use of boron in the synthesis and development of asymmetric methodologies and various biological and medicinal compounds has increased significantly over the last decade. This thesis reports the development of a novel diastereoselective reaction for the α-alkylation of chiral β-borylated …
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The Development of New Stereoselective Transformations Using Alkenyl Boronate Complexes
Anionic, tetravalent alkenyl boron-"ate" complexes have emerged as powerful reagents for the stereoselective synthesis of chiral boronic esters via multicomponent coupling. These complexes can react with electrophiles through a 1,2-metalate rearrangement process, resulting in the net addition of a …
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Iridium-Catalyzed Enantioselective Allylation of Alkenyl Boronates
Organoboronic esters are highly functionalizable synthetic intermediates owing to their unique reactivity that allows for pre-complexation with organometallic reagents to form boronates, which can then engage in bimolecular reactions. Furthermore, incorporation of boronic esters into their …