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Showing 1 to 3 of 3 for “"bis(Amidine)"”.
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NOVEL ETHYLENE-BRIDGED HEXADENTATE BIS(AMIDINES), BIS(AMIDINATES), AND MULTINUCLEAR COINAGE METAL BIS(AMIDINE) COMPLEXES
<p>A new series of hexadentate flexible bis(amidine) ligands (<strong>L<sup>1–6</sup></strong>H<sub>2</sub>) and the multinuclear coinage metal complexes <strong>1</strong>–<strong>5</strong> of <strong>L<sup>4</sup></strong>H<sub>2</sub> were synthesized and characterized. The synthesis of<strong> …
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Mirroring Enzymes: The Role of H-Bonding In HQuin-BAM Catalyzed Asymmetric Aza-Henry Reactions: A DFT Study into the Reactivity, Mechanism, and Origins of Selectivity
… investigation of a poorly understood chiral bis(amidine) (BAM) Brønsted acid catalyzed aza-Henry reaction between nitromethane and N-Boc phenylaldimine. The catalyst, in addition to acting as a Brønsted base, serves to simultaneously activate both the electrophile and the nucleophile through …
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BIFUNCTIONAL BF2 COMPLEXES OF POLYDENTATE BIS(AMIDINATES): SYNTHESIS, STRUCTURES, AND PHOTOLUMINESCENCE PROPERTIES
<p>Five novel bis(difluoroboryl)-bis(amidinates) <strong>L<sup>1-5</sup></strong>(BF<sub>2</sub>)<sub>2</sub> were synthesized in yields of 12−33%. Ethylene-linked bis(difluoroboryl)-bis(amidinates) represent an unprecedented class of new bifunctional fluorophores that have the potential to serve …