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Showing 1 to 2 of 2 for “"arylsilanolates"”.
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Preparative and mechanistic aspects of palladium-catalyzed cross-coupling reactions of alkali-metal arylsilanolates
The development of alkali-metal arylsilanolates as notable organometallic reagents for the preparation of biaryls has been realized through in depth mechanistic and preparative studies. The alkali-metal salts (potassium and sodium) of a large number of arylsilanols undergo smooth cross-coupling …
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I. Mechanistic significance of the Si-O-Pd linkage in the cross-coupling of organosilanolates; II. Applications of the water-gas shift reaction in organic synthesis
… cross-coupling reaction of alkenyl- and arylsilanolates. The combination of reaction kinetics (both stoichiometric and catalytic), solution and solid state characterization of arylpalladium(II) organosilanolate complexes, and computational analysis, enabled the formulation of a detailed …