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Showing 1 to 1 of 1 for “"anion-quadrupole interaction"”.

  1. Structure-Function Studies on Two Phosphoenolpyruvate Carboxylases

    … determined that in human PEPCK, Tyr235 forms an anion-quadrupole interaction with the carboxylate of PEP and thus positions the latter with respect to the enzyme-bound Mn²+ for optimal phosphoryl transfer and catalysis. We have also identified Pro82 as a catalytically influential residue in this …

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