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Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 20 of 187 for “"anion exchange"”.
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Anion exchange chromatographic analysis with conductometric detection
Thesis (M.S.)--Michigan State University. Dept. of Chemistry, 1971
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Site-Selective Anion Exchange in a Palladophosphorane
… The driving force for the favor toward the exchange at phosphorus has not been extensively explored, but hypotheses have been made which may entail the concept of hard-soft acid-base chemistry and the strength of the bonds involved.
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Ni Stability in Anion Exchange Membrane Fuel Cells
… platinum group metal (PGM) catalysts. An anion exchange membrane fuel cell (AEMFC) is one of many alternatives. The AEMFC provides an alkaline environment that enables the use of many non-platinum group metal (non-PGM) catalysts. This grants AEMFCs the potential to become Pt-free and thus …
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Treatment of Landfill leachates using anion exchange resins
… were conducted to evaluate the applicability of anion exchange resins to remove organic matter, UV quenching substance and organic nitrogen from landfill leachates. Leachate samples based on varying age and treatment methods were utilized. The anion exchange resins were found to work effectively …
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Design of anion exchange cellulose hydrogel for large proteins
… and performance as an immunosorbent. Here, anion exchange (DEAE) cellulose beads were derivatized by two different procedures (defined as A and B) and the changes in bead morphology were correlated with transport and sorption kinetics. The kinetic characteristics clearly defined a minimum of …
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Synthesis, properties and applications of single-component anion-exchange materials
… of these salts have been used in the past as anion-exchange extractants for attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy. Different crystallographic, electrochemical and spectroscopic parameters were analyzed to study properties like cation size and its …
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Transport properties of anion exchange membranes for fuel cell applications
… humidity, and cost effective. Although proton exchange membranes (PEM), such as Nafion® are highly conductive and chemically and mechanically stable, PEMs are not widely used in fuel cells due to the higher cost of fluoropolymers and the platinum metal catalysts. Anion exchange membranes (AEM) …
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Pyrometallurgical Oxide-Sulfide Anion Exchange for Improved Material Separation and Metal Production
… This can be accomplished via pyrometallurgical anion exchange chemistry. Revisiting separation pathways provides an added benefit; new separation chemistries can enable improved downstream processes for metal production without direct greenhouse gas emissions. Sulfur-based routes are expected to …
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Anion exchange study of the oxidation states of the halogens, including astatine
Thesis: Ph. D., Massachusetts Institute of Technology, Department of Chemistry, 1960
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Anion Exchange Membranes (AEMs), based on Polyamine Obtained by Modifying Polyketone, for Electrochemical Applications
Polymeric anion exchange materials can be key components for forming membranes for use in several electrochemical applications. Polyketones seem particularly promising as materials for making anion exchange membranes (AEMs), not only because the starting monomers, carbon monoxide and ethylene, are …
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Passive detection of phosphorus in agricultural drainage waters using reactive hybrid anion exchange resins
… method. Accordingly, polystyrene and polyacrylic anion exchange resins with different functional groups (i.e., strong-base and weak-base) were selected from a large pool of adsorbents (e.g., anion exchange resins, calcium and magnesium oxides, hybrid anion exchange resins, layered double …
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FIRST ROW TRANSITION METAL OXIDES AS ELECTROCATALYSTS FOR ANION EXCHANGE MEMBRANE FUEL CELLS AND ELECTROLYZERS
… transition metal oxides as candidates for anion exchange membrane fuel cells. These included a series of La-based perovskite oxides and a specific Co-Mn spinel oxide. For characterizing these systems, I employed electrochemical techniques such as cyclic voltammetry and rotating disk …
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Surface chemistry design and characterization of anion exchange and activated carbon fibers for critical contaminants removal
… explore the path to design a porous carbon with anion-exchangeable functional groups, and apply such system towards Cr(VI) removal in drinking water. A novel hybrid anion exchangeable activated carbons (HACAX) is synthesized through chemical modification of porous carbon surface. Ion exchange …
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Synthesis of anion exchange/activated carbon fiber hybrid materials for aqueous adsorption of toxic hexavalent chromium
… of Cr(VI), a unique hybrid activated carbon/anion exchange system (HACAX) has been developed for the first time in our group. HACAX was synthesized by methylation of PAN based Chemically Activated Carbon Fibers. The HACAX was characterized by BET, SEM, XPS,TGA and elemental analysis. The ion …
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UNDERSTANDING AND MODELING THE SORPTION ON ANION EXCHANGE RESINS USING POLY-PARAMETER LINEAR FREE-ENERGY RELATIONSHIPS AND PHASE CONVERSION
… developed a predictive model for the sorption of anionic organic contaminants from drinking water on three anion exchange resins: a strong polystyrenic (IRA-910), weak polystyrenic (IRA-96), and a strong polacrylic (A860). The model quantifies the individual mechanisms of sorption using …
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Sulfate removal from water produced during CO2 enhanced oil recovery, coal-bed methane recovery, and mining operations using anion exchange resins
… mining operations in the Illinois Basin using anion exchange resins. Equilibrium batch studies were conducted to compare commercially available strong base and weak base anion exchange resins of different type. Our results indicate that for optimal sulfate removal in high chloride solutions, …
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Part One: Catalytic Reactions of Anion-Exchange Resin Bound Dodecarhodium Triacontacarbonyl Dianion and Its Derivatives and Part Two: Properties and Reactions of Neutral Non-Polar Solvent Soluble Binuclear Complexes
The resin support was the Dowes 1-X8 anion exchange resin in the chloride form. Exchange of the cluster at room temperature under an inert atmosphere leads to intact Rh(,12) (CO)(,30)('2-) being bound. This material exhibits only limited activity for the hydroformylation of of 1-hexene, accompanied …
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