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Showing 1 to 2 of 2 for “"amidine-based catalysts"”.
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Kinetic Resolution of N-Acyl-b-Lactams, b-Lactams, and N-Acyl-Thiolactams using Amidine-Based Catalysts
… group has developed 4 consecutive generations of amidine-based catalysts: ABCs) that have engaged in a variety of enantioselective acylation transformations, mostly Type I: KR of various alcohols and lactams: and thiolactams) via asymmetric acylation) and Type III: enantioselective alcoholysis of …
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Part I. Anionic Acyl Transfer Catalysis;Part II. Enantioselective alcoholysis of Acyl Donors;Part III. Enantioselective N-acylation
… are widely used as acyl transfer catalysts. In contrast, anionic nucleophiles have been little explored in acyl transfer catalysis, although their high nucleophilicity may enable unique applications. In the course of my studies, 1,2,4-triazole anion was found to be an effective …