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Showing 1 to 1 of 1 for “"allylic silanes"”.
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Palladium catalyzed cross-coupling reactions of allyl- and vinylsilanes
… cross-coupling of γ-substituted allylic silanolates with aryl bromides was investigated. It was discovered that γ-selectivity is heavily influenced by the substituents at silicon. It is proposed that undergoing an activated pathway significantly lowers the selectivity of the …