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Showing 1 to 2 of 2 for “"alkyl nucleophiles"”.
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Nickel-catalyzed cross-coupling reactions involving secondary and tertiary alkyl nucleophiles
… some reports have demonstrated the use of C(sp3) nucleophiles and electrophiles in cross-coupling reactions. However, use of secondary and tertiary alkyl nucleophiles has remained a challenge due to competitive β-hydride elimination and slow transmetallation of bulky secondary and tertiary alkyl …
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Photoredox Generated Radicals In Csp2-Csp3 Bond Construction
The routine application of Csp3-hybridized nucleophiles in cross-coupling has been an ongoing pursuit in the agrochemical, pharmaceutical, and materials science industries for over 40 years. Unfortunately, despite numerous attempts to circumvent the problems associated with alkyl nucleophiles, …