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Showing 1 to 2 of 2 for “"adsorbate vibrations"”.
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Selective excitation of adsorbate vibrations on dissipative surfaces
… selective infrared (IR) excitation of molecular vibrations is a powerful tool to control the photoreactivity prior to electronic excitation in the ultraviolet / visible (UV/Vis) light regime ("vibrationally mediated chemistry"). For adsorbates on surfaces it has been theoretically predicted that …
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Vibrationally enhanced associative photodesorption of H2 (D2) from Ru(0001) : quantum and classical approaches
… These hot electrons then transfer energy to adsorbate vibrations which leads to desorption. In fact, adsorbate vibrations are strongly coupled to metal electrons, \textit{i.e.}, through non-adiabatic couplings. This means that, surfaces introduce additional channels for energy exchange which …