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Showing 1 to 20 of 23 for “"acid-base interactions"”.
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Gas Phase Lewis Acid-Base Interactions
Made available in DSpace on 2014-12-09T17:35:07Z (GMT). No. of bitstreams: 1 6503665.pdf: 4735633 bytes, checksum: 52109a08d7e92e8f90ec7b5e4956af0d (MD5) Previous issue date: 1964
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Calorimetric Investigations of Lewis Acid-Base Interactions
Made available in DSpace on 2014-12-10T23:01:56Z (GMT). No. of bitstreams: 1 7500316.pdf: 3856228 bytes, checksum: 8a099174383142d44c149312c85aecba (MD5) Previous issue date: 1974
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Investigation of acid/base interactions in adhesion
The fundamental study of Lewis acid/base interactions presented in this dissertation demonstrates the role of these interactions in adhesive phenomena. The model systems investigated were representative of real substrates and soft, viscoelastic adhesives where, in one case, favorable acid/base …
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ACID-BASE INTERACTIONS IN AMORPHOUS SOLID DISPERSIONS: FORMULATION STRATEGY FOR TYROSINE KINASE INHIBITORS
… Yang. Ph.D., Purdue University, December 2015. Acid-base Interactions in
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The investigation of acid/base interactions in the adhesion of carbon fibers to thermoplastic matrices
Lewis acid/base interactions were shown to play an important role in the optimization of the interfacial adhesion of reinforcing carbon fibers to thermoplastic polymer matrices. Inverse gas chromatography (IGC) and x-ray photoelectron spectroscopy (XPS) were used to characterize the acid/base …
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Part One: Nuclear Magnetic Resonance (Nmr) and Infrared Investigations of Lewis Acid-Base Interactions. Part Two: Extension of the E-and-C-Equation to Novel Systems
Made available in DSpace on 2014-12-10T23:01:33Z (GMT). No. of bitstreams: 1 7317424.pdf: 7834453 bytes, checksum: fe31366f5b6a5facff94ea980a763cba (MD5) Previous issue date: 1972
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Spectroscopic Studies on Lewis Acid-Base Interactions. Part One: Epr Studies of Lewis Acids and Bases Interaction. Part Two: Kinetic Studiesof Chemical Reactions by Calculation of Exchange-Broadened Nmr-Lineshapes
Made available in DSpace on 2014-12-10T23:01:30Z (GMT). No. of bitstreams: 1 7317152.pdf: 2532411 bytes, checksum: 053b8ca1ee02f9e43f6a90fbb46f717d (MD5) Previous issue date: 1972
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Nuclear Magnetic Resonance Studies of Acid-Base Interactions: Part I. Proton Magnetic Resonance Studies of Hydrogen Bonding. Part Ii. J(boron-11-Fluorine-19) in Boron Trifluoride and Its Derivatives
Made available in DSpace on 2014-12-09T17:35:02Z (GMT). No. of bitstreams: 1 6503576.pdf: 4257982 bytes, checksum: ea83a01e8f7216d223d4c2ccc7555081 (MD5) Previous issue date: 1964
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Lewis Acid-Base Interactions. Part One: The Extension and Limitations of The Frequency Shift-Enthalpy Correlations of Hydrogen Bonding Systems. Part Two: Extension and Refinement of the E and C Correlation
Made available in DSpace on 2014-12-10T23:01:06Z (GMT). No. of bitstreams: 1 7114976.pdf: 3543850 bytes, checksum: 8d6a294c2dfd60076811ec9cf0a7ac59 (MD5) Previous issue date: 1970
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A Study of Lewis Acid-Base Interactions: Part 1 - a Tin-119 Moessbauer and Tin-119 Nmr Study of the 1: 1 Lewis Base Adducts of Trimethyltin Chloride. Part 2 - a Calorimetric, and F(19), B(11), and H(1) Nmr Study of the Lewis Base Adducts of Boron-Trifluoride
Made available in DSpace on 2014-12-09T17:36:13Z (GMT). No. of bitstreams: 1 6910722.pdf: 5353101 bytes, checksum: 36aca5a579ee06afcbff0064c0a9f87d (MD5) Previous issue date: 1968
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Colorimetric Sensor Array: Do I See What You Smell
… defined color changes due to stronger chemical interactions: ligation to metal ions, Lewis or Bronsted acid-base interactions, hydrogen bonding, etc. Striking visual identification of a wide range of VOCs are easily made at part per billion (ppb) levels with extremely low error rates for Toxic …
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Development of nitrogen doped resorcinol-formaldehyde gels for carbon capture
… in order to enhance the favourable Lewis acid-base interactions with CO2. Melamine (M) is used in order to incorporate Nitrogen (N) into the gel structure; and partially replace the Resorcinol (R) traditionally used, resulting in a Melamine-Resorcinol-Formaldehyde (MRF) gel. Repeatability …
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Earth-Abundant Thin-Film Devices for Photovoltaic and Electrochemical Applications
… a wide range of metal chloride species via Lewis acid-base interactions. This facilitated a novel silver and germanium co-alloying strategy in CZTS which led to devices with record high performance metrics. Electrochemical oxidation is a promising technology to remediate pharmaceuticals in …
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Removal of polymer coating with supercritical carbon dioxide
… fluid applications is nearly always based on a trial and error approach, and frequently requires evaluating each operation on a case-by-case basis. A significant improvement in this approach is accomplished with the development of a framework in which polymer-CO2 interactions can be …
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Synthesis and Application of Air-Stable Secondary Phosphine Oxide, Oxime, and Amine-Phosphine Palladium(II) Complexes in Transfer Hydrogenation and Cross-Coupling Reactions
… containing functional groups that introduce acidic/basic sites proximal to the metal center can participate through acid-base interactions with the substrates. Multifunctional ligands have proven to be efficient in numerous transition-metal-catalyzed processes. We focused on synthesizing …
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Aromaticity Across States: A Framework for Reactivity and Structure in Organic Systems
… how excited-state aromaticity modulates Lewis acid–base interactions. We show that adducts containing [4n] π-electron rings (e.g., boroles) undergo photodissociation, stabilized by aromaticity gain in the excited state, whereas [4n+2] systems (e.g., borepins, pyrroles) favor photoassociation …
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Functionalization of Metal Oxide Surfaces through Chemical Reactions and Physical Adsorption
… of the adsorbed siloxanes by the Lewis acidic centers, followed by the coupling of silanols to the surface to produce grafted siloxanes.</p> <p>We then explored Phthalocyanines (Pcs), an interesting class of catalytically active molecules with unique spectroscopic, photoelectric, and …
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The Characterization of Cationic Pseudostationary Phases for Electrokinetic Chromatography
… center caused differences in the cohesivity and acid/base interactions of the pseudostationary phase. Finally, two cationic carbohydrate based surfactants were used as a MEKC pseudostationary phase for the first time. The newly characterized glucocationic phases provided differences in …
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The Characterization of Cationic Pseudostationary Phases for Electrokinetic Chromatography
… center caused differences in the cohesivity and acid/base interactions of the pseudostationary phase. Finally, two cationic carbohydrate based surfactants were used as a MEKC pseudostationary phase for the first time. The newly characterized glucocationic phases provided differences in …
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Rotavirus interactions with silica and natural organic matter
… systems raises fundamental questions regarding interactions with surfaces that may affect its fate and transport. Consequently, the main objectives of this study were: 1) investigate the mechanisms that govern rotavirus interactions with environmental surfaces; and 2) examine the role of …
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