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Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 9 of 9 for “"Zn(II) complexes"”.
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Exploring Photocatalytic and Electrocatalytic Reduction of CO2 with Re(I) and Zn(II) Complexes and Attempts to Employ a Novel Carbene Ligand to this Endeavor
… as a reduction product. Furthermore, synthesized Zn(II) phosphino aminopyridine complexes are structurally and computationally characterized as well as observed to function as unprecedented electrocatalysts for the reduction of CO2 to formic acid and CO. Lastly, with the importance and popularity …
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Novel Schiff-base and Benzamide N,O-Donor Ligands for Development as Fluorionophores and Selective Metal Ion Binders
… reacted with various MX2 salts (M = Cu, Ni and Zn and X = perchlorate, acetate and chloride). In every case except one (where a coordination polymer was formed), hydrolysis of the ligand occurred to give the liberated amine and aldehyde. The amine bound to the metal ion to give the appropriate …
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Hydrosilylation and hydroboration catalyzed by imido-hydride complexes of molybdenum (IV)
… reactivity of novel Mo(IV) imido hydride complexes (Cp)(ArN)Mo(H)(PMe3) (1) and (Tp )(ArN)Mo(H)(PMe3) (2). Both 1 and 2 catalyze hydrosilylation of a variety of carbonyls. Detailed kinetic and DFT studies found that 1 reacts by an unexpected associative mechanism, which does not involve …
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Synthesis and reactivity studies of mono-, bi-, and trimetallic complexes supported by oxidatively-resistant polyanionic ligands
… to support mono-, bi-, and trimetallic complexes are presented. Selective single metal ion insertion into the cryptand was achieved to generate the mono-Co(II) and Zn(II) complexes that contain proximal hydrogen-bonding networks enforced by the carboxamide N-H groups of the pre-organized …
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The Development of Functionalized Metal Complexes as Selective Phosphopeptide Molecular Recognition Agents
The development of dimetallic metal complexes into functional and selective recognition agents for monophosphorylated peptides is described. The development of dimetallic metal complexes into functional and selective phosphopeptide recognition agents is described. Scaffold functionalization was …
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Metal complexes of anti-tubercular drugs
… towards existing drugs. In some cases, metal complexes are known to improve the bioavailability of drugs. Hence the present study looks at the use of metal complexes of anti-tubercular drugs to improve the permeability and bioavailability of the drugs. The anti-tubercular drugs isoniazid …
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Development of copper based anti-inflammatory drugs: histodine derivatives
… the ligand (glycyl-L-histidine) and the ligand complexes with Cu(II), Ni(II) and Zn(II) were investigated with glass electrode potentiometry and isothermal titration calorimetry at 25±0.01oC at an ionic strength 0.15M with NaCl. Potentiometric studies show that glycyl-L-histidine has three …
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Magnetically Interesting Coordination Complexes Based on Macrocyclic Ligands
… and study of select 3d and/or 4f coordination complexes prepared from crown ether and Schiff-base dual compartmental macrocycles are described herein, working towards the discovery and study of new families of macrocyclic-based single molecule magnets (SMMs). Chapter 1 introduces the general …