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Showing 1 to 2 of 2 for “"Zinkenzymen"”.
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Polar Tris(pyrazolyl)borates for the modeling of Zinc metalloenzymes in aqueous solution
The ultimate aim of this work was to understand the importance of secondary interactions of hydrophilic nature in the catalytic activity of zinc metalloenzymes. The zinc complexes of novel poly(pyrazolyl)borate ligands bearing polar substituents on the 3-position of the pyrazoles were expected to …
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Design of new tripodal ligands to advance the biomimetic Zinc chemistry
The goal of this work was the synthesis of a ligand system which coordinates zinc with the same features as those showed by the enzymes. This ligand was to be water soluble, was to form a hydrophobic cavity around zinc and was to provide additional functional groups with hydrogen bonding …