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Showing 1 to 2 of 2 for “"Zinc enzymes"”.
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Design of new tripodal ligands to advance the biomimetic Zinc chemistry
… synthesis of a ligand system which coordinates zinc with the same features as those showed by the enzymes. This ligand was to be water soluble, was to form a hydrophobic cavity around zinc and was to provide additional functional groups with hydrogen bonding properties. Several zinc complexes of …
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Polar Tris(pyrazolyl)borates for the modeling of Zinc metalloenzymes in aqueous solution
… hydrophilic nature in the catalytic activity of zinc metalloenzymes. The zinc complexes of novel poly(pyrazolyl)borate ligands bearing polar substituents on the 3-position of the pyrazoles were expected to contribute to this. These comprise the carboxyester substituted BpC(O)OR,Me (R = Me, Et), …