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Showing 1 to 1 of 1 for “"Wagner-Meerwein Rearrangement"”.
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Part A: Studies Towards Total Synthesis of an Anticancer and Antifungal Natural Product, Pseudolaric Acid B; Part B: Synthesis and Biological Evaluation of Berkeleyamide a and Its Derivatives
… give a bicyclo [2.2.2] acid, and a cationic 1,2- rearrangement. Series of functional group transformation reactions of the DA adduct, epoxidation, a tandem ring-opening-ring closing event, decarboxylation, and an enhanced Wagner-Meerwein rearrangement afforded a bicyclo [3.2.1] core 3.22. …