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Showing 1 to 2 of 2 for “"VHAE"”.
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Probing Solvation Shell Dynamics of Organometallic Complexes via Two-Dimensional Infrared Spectroscopy
… arising from the vibrational heavy atom effect (VHAE). The solvation shell was further impacted by the fluxional nature of some of the complexes. The deviation due to fluxional structure was especially pronounced in Fe₃(CO)₁₂, leading to larger inhomogeneous amplitudes relative to the other …