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Showing 1 to 5 of 5 for “"Unrestricted Hartree-Fock (UHF)"”.

  1. Catalysis by transition metal compounds

    … surfaces, were calculated using the ab initio Unrestricted Hartree-Fock (UHF) method. The electronic structure of the bulk solid was studied through band and cluster models. The bulk electronic structure computed predicts insulating behavior for cobalt oxide and agrees with experimental optical …

    uiuc Repository record for Catalysis by transition metal compounds (opens in a new tab)

  2. Implementation of Kunz-Klein localization in icecap and an application to the problem of off-center isovalent substitutional impurities in alkali halides

    … the computer program HADES and by means of an Unrestricted Hartree-Fock (UHF) cluster embedded in a shell model lattice using the computer program ICECAP. For the case using HADES, off-center behavior was predicted, and the resulting potential was used to predict the tunnelling splitting of the …

    uiuc Repository record for Implementation of Kunz-Klein localization in icecap and an application to the problem of off-center isovalent substitutional impurities in alkali halides (opens in a new tab)

  3. Spin projection of semi-empirical and ab initio unrestricted Hartree-Fock wavefunctions

    … calculate projected semi-empirical and ab initio unrestricted Hartree-Fock (UHF) wavefunctions. The electronic spectra of naphthalene, anthracene, naphthacene and pentacene were calculated using the Pariser-Pople-Parr (PPP) Π-electron approximations and both UHF and configurational interaction …

    vt Repository record for Spin projection of semi-empirical and ab initio unrestricted Hartree-Fock wavefunctions (opens in a new tab)

  4. Development and Application of Coupled Cluster Ground- and Excited-State Models

    … radicals. We define the method for both spin-unrestricted Hartree-Fock (UHF) and spin-restricted open-shell Hartree-Fock (ROHF) reference determinants and discuss its efficient implementation in the PSI3 program package. The program is streamlined to use at most O(N7) computational steps and …

    vt Repository record for Development and Application of Coupled Cluster Ground- and Excited-State Models (opens in a new tab)

  5. Ab initio Hartree-Fock and many body perturbation theory calculation of the energies of the excited states of some materials

    In this thesis the use of the Unrestricted Hartree-Fock technique augmented by many body perturbation theory techniques and symmetry projection methods in the study of the energies of the excited states of atomic, molecular and solid state systems is investigated. A perturbation method for finding …

    uiuc Repository record for Ab initio Hartree-Fock and many body perturbation theory calculation of the energies of the excited states of some materials (opens in a new tab)