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Showing 1 to 20 of 29 for “"UV-Vis spectra"”.
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ΣΥΝΘΕΣΗ, ΦΑΣΜΑΤΟΣΚΟΠΙΚΗ ΚΑΙ ΚΡΥΣΤΑΛΛΟΓΡΑΦΙΚΗ ΜΕΛΕΤΗ ΤΗΣ ΔΟΜΗΣ ΚΑΙ ΘΕΩΡΗΤΙΚΑ ΜΟΝΤΕΛΑ ΣΥΜΠΛΟΚΩΝ ΤΩΝ ΣΟΥΛΦΟΝΥΛΟΥΡΙΩΝ ΜΕ D8,D9 ΚΑΙ D10 ΜΕΤΑΛΛΟΙΟ...
… ANALYSIS, MAGNETICALLY AND SPECTROSCOPICALLY (IR SPECTRA, UV-VIS SPECTRA, EPR SPECTRA, NMR SPECTRA, MASS SPECTRA), THERMAL ANALYSIS, X-RAY STRUCTURE ANALYSIS, THEORETICAL CALCULATIONS OF THE MOLECULAR STRUCTURE, CONDUCTOMETRIC AND POTENTIOMETRIC MEASUREMENTS OF THEIR SOLUTIONS IN MIXED SOLVENTS …
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Photochemistry of 5-Membered Heteroaryl(trifluoromethyl)carbenes in Low Temperature Matrices
… led us to a new realm of UV-vis transparent diazirines, which behave as normal diazirine photochemically, but have very weak n<em>f</em>à<em>f</em>x<em>f</em>nabsorptions which are not visible in experimental UV-vis spectra. Also, we were able to synthesize diazirine …
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Multi-Method Investigation of the Mechanism of Surfactant-Induced Chromatotropism of Metal-Chelometric Dye Complexes
… which certain surfactants change the ultraviolet-visible (UV-vis) spectroscopic properties of certain metal-dye complexes has been largely ignored in the chemical literature. In this manuscript a model is developed to describe this mechanism. Intramolecular forces among surfactant molecules and …
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Reactions of Congo Red and Azo Dye Congeners With Formaldehyde
… exposed to formaldehyde, retention times and UV-Vis spectra were consistent with the identification of the unknown yellow product as the N-formyl product. Isolation of the yellow product from the reaction mixture with formaldehyde was successfully achieved with the half-dye analog of Congo red …
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Spectral and Physicochemical Characteristics of nC60 in Aqueous Solutions
… transmission electron microscopy (TEM), and UV-Vis spectroscopy. nC₆₀ produced in the presence of carboxylate differs from that produced in water alone (aq/nC₆₀) with respect to surface charge, average particle size, interfacial properties, and UV-Vis spectroscopic characteristics. …
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Green synthesis of silver nanoparticles using Moringa oleifera extracts and their evaluation against antibiotic resistant strains of escherichia coli and staphylococcus aureus
… Synthesized AgNPs were characterized using UV-vis spectroscopy, fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Disc diffusion method was used for initial screening of antibacterial activities and their minimum inhibitory concentration (MIC) was …
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Photodegradation of biopolymer doped with titanium dioxide (TiO2) as ultraviolet (UV) stabilizer
… the resistance of the biopolymer to ultraviolet (UV) light exposure. The virgin oil (VO) and waste oil (WO) was converted into biomonomer. By adding biomonomer with an appropriate amount of 4, 4’-methylene diphenyl diisocyanate (MDI) and solvent, the virgin oil polymer (VOP) and waste oil polymer …
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Photodegradation of biopolymer doped with titanium dioxide (TiO2) as ultraviolet (UV) stabilizer
… the resistance of the biopolymer to ultraviolet (UV) light exposure. The virgin oil (VO) and waste oil (WO) was converted into biomonomer. By adding biomonomer with an appropriate amount of 4, 4’-methylene diphenyl diisocyanate (MDI) and solvent, the virgin oil polymer (VOP) and waste oil polymer …
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Selective Laser-Induced Oxidation of Carbon Chain Molecules in Cryogenic Matrices
… of those carbon molecules which have known UV/VIS absorptions. For this purpose we trapped the molecules of carbon vapor in non-inert matrices(O2, Ar-O2). Upon matrix annealing, molecular growth took place leading to a mixture of linear carbon species up to C17. The output of an excimer-dye …
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Cyanide-bridged polynuclear complexes
… by X-ray single crystal determination, IR, UV-Vis and cyclic voltammograms, respectively. The three mixed valent dinuclear complexes display metal- metal charge transfer (MMCT) bands in the visible region. Some of MMCT properties in the complexes have been analyzed. The cyanide-bridged trans …
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Identification of Molecules by Spectral Imaging
<p>Spectral imaging is a powerful technique which uses the wavelength to identify/quantify the exact location and amount of the molecules. It facilitates the identification of materials and studying their properties through analyzing the way they interact with light. The study of light interaction …
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Application of factor analysis to spectroscopic methods
… The application of factor analysis to the UV-Vis spectra of a series (quaternary mixtures of transition metal ions is shown. The number of ions in the system is determined and the identities of the ions assigned using target testing. The effect of inadequate sampling intervals of the data …
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Quantum mechanical study of molecular switches : electronic structure, kinetics and dynamical aspects
… and quantitative appearance of calculated UV/Vis spectra, as well. Finally, an explicit treatment of a solid substrate was demonstrated for the conformational switching, by scanning tunneling microscope, of a 1,5-cyclooctadiene (COD) molecule at a Si(001) surface, treated by a cluster …
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Electronic Spectroscopy, Photochemistry, And Reactivity Of Isoprene-Derived Criegee Intermediates
… Criegee intermediates exhibit broad ultraviolet-visible (UV-vis) spectra with strong absorption (ca. 10-17 cm2 molec-1). Electronic excitation of Criegee intermediates results in nonadiabatic coupling to repulsive potentials and prompt release of O 1D products. Velocity map imaging is used to …
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Chemical functionalization and modification of Au clusters
… of the reducing agent. Furthermore, based on UV-Vis spectroscopy, three absorption peaks at around 690, 440, and 390 nm were observed at 0.30 M of the reducing agent, which are spectroscopic fingerprints of Au25 NCs and are strongly suggestive of the formation of fluorenylmethyloxycarbonyl …
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Polyelectrolyte multilayers for plasmonics and picosecond ultrasonics
… of polyelectrolytes, whose ratio affects the spectral position of the LSP resonance. Measured UV-VIS spectra showed the shift of the LSP absorption peak as a function of the cover layer thickness of the particles. The data are modeled using an average dielectric function instead of the …
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A STUDY OF THE ELECTRONIC PROPERTIES OF SOME HETEROCYCLIC COMPOUNDS AND THE THERMAL DECOMPOSITION OF METHYLATED THIOBUTYROLACTONES
… corresponding polymers. From the photoelectron spectra, four bands corresponding to four ? molecular orbitals (MO) were located in the low energy region between 7 and 12eV. Careful examination of the Hel/Hell band intensity variations and band profiles showed that two of these orbitals were …
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Characterization and technical studies of semiconductor nanoclusters synthesized within polymer films
… X-ray fluorescence, electron microscopy, and UVVis spectroscopy. The cluster size and hence its optical properties could be controlled by varying processing parameters such as the reaction temperature, the presence of coordinating bases, and the time of exposure to H2S. A model was developed …
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Implications For the Role of the Peroxoferric Intermediate In the Second Step of Nitric Oxide Synthase Derived From the Reactivity of P450-Cam With Camphor-5-Oxime and Characterization of the Heme Iron Coordination Structures of Tyrosine- and Histidine-Ligated Heme Enzymes Using Magnetic Circular Dichroism Spectroscopy
… <p>Magnetic circular dichroism (MCD) and UV-Visible (UV-Vis) absorption spectroscopy have been used to characterize the heme-iron coordination structure of (A) several tyrosinate-ligated heme enzymes and (B) the high potential (HP) and low potential (LP) heme centers of the diheme …
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Synthesis and characterisation of mononuclear and dinuclear rhenium carbonyl complexes
… a blue shift of both the absorption and emission spectra when compared to [Re(CO)3(bpy)Cl]. Chapter Three is discusses the synthesis of the rhenium(I) tricarbonyl complexes of 3-(pyrazin-2-yl)-l,2,4-triazoles, analogous to those described in Chapter Two. The complexes were characterised by NMR and …
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