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Showing 1 to 2 of 2 for “"Trispyrazolylborates"”.
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Rational design of hydrogen-free catalytic active sites
Materials that are organic-based and exhibit oxidative catalytic activity, including free-radical pathways, while being refractory to the activated oxygen species are not known. The synthesis of several classes of such materials, their electronic and structural characterizations as well as …
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Polar Tris(pyrazolyl)borates for the modeling of Zinc metalloenzymes in aqueous solution
The ultimate aim of this work was to understand the importance of secondary interactions of hydrophilic nature in the catalytic activity of zinc metalloenzymes. The zinc complexes of novel poly(pyrazolyl)borate ligands bearing polar substituents on the 3-position of the pyrazoles were expected to …