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Showing 1 to 9 of 9 for “"Trifluoromethylation"”.

  1. DESIGN AND SYNTHESIS OF PURINE BASED NEUROPROTECTORS AND NOVEL SYNTHETIC METHODS FOR THE TRIFLUOROMETHYLATION OF ALDEHYDE HYDRAZONES

    Aryal, PuspaMissouri University of Science and Technology

    … species (ROS).</p> <p>The C(sp<sup>2</sup>−H)-trifluoromethylation of hydrazones would give access to the αtrifluoromethylated hydrazones that can serve as intermediates in the synthesis of pharmaceutically interesting, fluorinated compounds. Herein, we demonstrate two different synthetic …

    must-thes Repository record

  2. Carbon-trifluoromethyl bond forming reactions and palladium-catalyzed cyanation of (hetero)aryl halides

    Senecal, Todd D. (Todd Dale)Massachusetts Institute of Technology2013

    … to the development of the first system for the trifluoromethylation of aryl chlorides. Chapter 2 A method for the oxidative trifluoromethylation of (hetero)aryl boronic acids is reported. Bench top setup and visual reaction monitoring makes this process particularly well suited to medicinal and …

    mit Repository record

  3. Fluorine-containing fullerenes and endometallofullerenes: synthesis, structure, and spectroscopic characterization

    Shustova, Natalia Borisovna, author, Strauss, Steven H., advisor, Anderson, Oren P., committee member, Szamel, Grzegorz, committee member, Elliott, Cecil Michael, committee member, Roess, Deborah A., committee memberColorado State University. Libraries2010

    … to have superior electron-accepting properties. Trifluoromethylation of a sample of insoluble hollow higher fullerenes resulted in the structural characterization of several new dodecakis(trifluoromethyl) fullerene compounds, and this led to the first experimental observation of fullerenes …

    colostate Repository record

  4. Direct ⍺-C–H Functionalisation of Cyclic Alkylamines

    Phillips, RachelUniversity of Cambridge2025

    … intermediates enabled the α-alkylation and α-trifluoromethylation across a range of piperidine-based systems. Furthermore, the formal C–H functionalisation sequence was successfully applied to the late-stage modification of complex bioactive molecules, underscoring the potential of this …

    cambridge Repository record

  5. Part I: Design, synthesis, and studies of novel age-inhibitors and age-breakers; Part II: Novel synthetic methods for organofluorine compound

    Mehta, JatinMissouri University of Science and Technology

    … We have also developed a novel NHC-catalyzed trifluoromethylation of aromatic N-tosyl aldimines with electron-withdrawing as well as electron-donating groups on the aryl ring. We have synthesized a series of novel purine-based triazole derivatives as potential CDK-inhibitors and characterized …

    must-thes Repository record

  6. Carbon dots as sustainable photocatalysts for organic synthesis

    Lage, AvaUniversity of Cambridge2023

    … potential of this reaction, the net-oxidative trifluoromethylation was coupled to H<sub>2</sub>-evolution, thereby generating two products simultaneously: a trifluoromethylated aryl and feedstock for hydrogenation. Chapter 3 subsequently introduces CDs as photocatalysts for net-reductive …

    cambridge Repository record

  7. Development of Novel Methods for the Installation of Trifluoromethyl/Boryl and 1,2,4-Oxadiazole Moieties

    Jos, SwethaVirginia Tech2022

    … via a stereoretentive radical trifluoromethylation with inexpensive reagents NaSO2CF3 and TBHP with copper catalysis at room temperature. Under these conditions, a wide substrate scope afforded the (E)‐diastereomer exclusively in moderate to good yield. The reaction products' …

    vt Repository record

  8. Modifying electronic and solid-state properties of fullerenes, polycyclic aromatic hydrocarbons, and perylene diimides

    Clikeman, Tyler T., author, Strauss, Steven H., advisor, Rumbles, Garry, advisor, Shores, Matt P., committee member, Chen, Eugene Y.-X., committee member, Bailey, Travis, committee member, Sites, Jim, committee memberColorado State University. Libraries2015

    … and characterized for the first time. Trifluoromethylation of azulene systematically increases the electron-withdrawing strength and affects solid-state packing motifs. The molecular structures and solid-state packing of four other families of fluorine-modified polycyclic aromatic …

    colostate Repository record

  9. Development and Application of N-Trifluoromethyl NHC Ligands for Transition-Metal Catalysis

    Engl, Pascal StephanETH Zurich2017

    ethz Repository record