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Showing 1 to 2 of 2 for “"Trichodermamide B"”.
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Progress towards the enantioselective total synthesis of trichodermamide B
Trichodermamide B is an unusual modified dipeptide natural product, with very promising anticancer activities. While the biosynthesis of this molecule is unknown, it is proposed herein that it is formed in vivo through direct oxidation of phenylalanine to the arene oxide or arene dioxide …
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Synthetic studies towards trichodermamide B: expedient synthesis enabled by arene oxide equivalents
Trichodermamide B, isolated from the marine fungus Trichoderma virens in 2003, is a potent anti-cancer agent and with complex molecular architecture. It is hypothesized herein that this molecule may be derived in nature from phenylalanine via a benzene oxide intermediate. Utilizing a bioinspired …