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Showing 1 to 3 of 3 for “"Transition metal alkane complexes"”.
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Pentamethylcyclopentadienyl Osmium Chemistry: An Approach to Transition Metal Alkane Complexes
Protonation of $\rm(C\sb5Me\sb5)Os(PMe\sb3)\sb2Me$ with $\rm HBF\sb4{\cdot}Et\sb2O$ at room temperature affords the Os$\sp{\rm IV}$ alkyl hydride complex $\lbrack\rm(C\sb5Me\sb5)Os(PMe\sb3)\sb2Me(H)\rbrack\lbrack BF\sb4\rbrack.$ Protonation of $\rm(C\sb5Me\sb5)Os(dmpm)Me$ at ${-}120\sp\circ$C with …
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Osmium alkane complexes: Synthesis, characterization, and isotopic labeling studies
Submission published under a 24 month embargo labeled 'Closed Access', the embargo will last until 2025-05-01
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Low-temperature protonation studies of transition metal alkyl complexes and the synthesis and characterization of early transition metal PCP pincer complexes and two-coordinate alkylamido complexes
We recently reported NMR studies of an osmium alkane complex, [Cp*Os(DFMPM)(CH4)]+, where Cp* is pentamethylcyclopentadienyl and DFMPM is bis(bis(trifluoromethyl)phosphino)methane. As part of an effort to continue these studies, the procedures to synthesize the DFMPM ligand and the Cp*Os(DFMPM)Br …