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Showing 1 to 4 of 4 for “"Transition Metal Hydrides"”.
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Alkane Elimination Reactions between Transition Metal Hydrides and Rare-Earth Alkyls
In the present work various transition metal hydrides were examined regarding their potential to form unsupported bonds towards rare-earth metals. Selected rare-earth alkyls were reacted with the metal hydrides in question. Motivated by previous results of the Kempe group in which the alkane …
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I. Radical Cyclizations Mediated by Transition Metal Hydrides II. Study toward the Total Synthesis of Pluraflavin A III. Cytoprotective Polyacetylenes Inspired by Panaxytriol
… describes radical cyclizations mediated by transition metal hydrides. CpCr(CO)₃H and (H₂O)₂Co(dmgBF₂)₂ under H₂ gas catalyzed the radical cyclization of 1,6-dienes to form 5- and 6-membered rings and the cyclization of a 1,6,11 triene to form a substituted decalin. Vanadium hydrides of the …
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Solid State Studies of [ReH9]-2 Complexes from Ambient to Extreme Conditions: High Volumetric Capacity Hydrogen Storage
… has the potential to energy system. Solid state transition metal hydrides based on Re and transition metals are very attractive materials for hydrogen and energy storage due to their large volumetric capacity, providing a safe and efficient way of storing hydrogen. The [ReH9]-2 ion continues to …
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A Matrix Isolation Spectroscopic Investigation of the Reaction Products of Transition Metal Centres With Ethene and Water
… new products of C-H bond insertion by the metal atom, including additional H-V-C2H3 conformational isomers, and H2V(η2-C2H2) products are observed in the infrared spectrum. Additionally, the formation of ethane is evident as a major product immediately following deposition of V + C2H4 + H2O …