Global ETD Search

Kinetics and Mechanism of the Reaction of 4,4'-Dimethoxythio Benzophenone With Grignard Reagents

Fradenburgh, Sharon AnnUniversity of Illinois at Urbana-Champaign2014

… stopped-flow spectroscopy. The reaction of this thioketone with methylmagnesium bromide in ether at 25.0(DEGREES)C was found to be first order in thioketone and first order in Grignard, with a second-order rate constant of 0.047 (+OR-) 0.002 s('-1)M('-1). The mechanism proposed to account for the …

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Synthesis and chemistry of thione-iron carbonyl complexes

Chan, Albert Shil-Kwan

… were produced using thiofenchone as the reactant thioketone.</p>

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The Behavior of α-Thiaketones and α-Aminoketones under Conditions of the Clemmensen Reduction and Electrolytic Reduction

Figueras, JohnUniversity of Illinois at Urbana-Champaign1952

uiuc Repository record for The Behavior of α-Thiaketones and α-Aminoketones under Conditions of the Clemmensen Reduction and Electrolytic Reduction (opens in a new tab)