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Showing 1 to 8 of 8 for “"Tetrazolate"”.
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Synthesis And Characterization Of Metal Complexes Containing Tetrazolate, Poly(tetrazolyl)borate, And Aryl Pentazole Ligands As High Energy Density Materials
<p>Heavier alkaline earth metal tetrazolates have been prepared as cryatals contain aqua ligands and as anhydrous powders, and were characterized by spectral and analytical methods. Potassium bis(tetrazolyl)borate complexes K(BH<sub>2</sub>(RCN<sub>4</sub>)<sub>2</sub>)(H<sub>2</sub>O)<sub>n</sub> …
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Synthesis And Characterization Of Metal Complexes Containing Tetrazolate, Poly(tetrazolyl)borate, And Poly(azolyl)aluminate Ligands As High Energy Density Materials
<p>A series of heavy alkaline earth metal tetrazolate complexes has been synthesized that contain metal ions saturated by aqua ligands. Tetrazolates with small ring-core carbon substituents favor formation of two dimensional polymers with u3-coordination of the tetrazolate to the metal centers. …
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Synthesis and Characterisation of N-substituted Pyrrole Monomers and Polypyrrole Films
… moiety, tricarbonyl cyclopentadienyl N-2-(5-tetrazolatephenyl) molybdenum(II), tricarbonyl cyclopentadienyl N-2-(5-tetrazolate-2-thiophene) molybdenum(II) and tricarbonyl cyclopentadienyl N-2-(5-tetrazolate-1-benzyl) molybdenum(II) were synthesised via cycloaddition chemistry employing sodium …
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New materials for electrochemiluminescence
… on new synthesized Ru(II) complexes containing tetrazolate based ligands. ECL emission has been investigated in solution and in solid thin films. The effect of the chemical protonation of the tetrazolate ring on ECL emission has been also investigated evidencing the possibility of a catalytic …
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New Materials For Electrochemiluminescence
… on new synthesized Ru(II) complexes containing tetrazolate based ligands. ECL emission has been investigated in solution and in solid thin films. The effect of the chemical protonation of the tetrazolate ring on ECL emission has been also investigated evidencing the possibility of a catalytic …
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Synthetic and Post-Synthetic Methods towards Fine Tuning the Chemical and Physical Properties of Metal-Organic Frameworks
… CoBTDP exhibits O₂ reactivity, unlike its all-tetrazolate counterpart, underscoring the role of linker design in tuning MOF function. Together, these studies demonstrate how careful control over MOF synthesis and post-synthetic modification can be used to fine-tune redox behavior, framework …
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Investigating the Cluster Chemistry of α-Methyl-2-pyridine methanol (mpmH) with Select 3d Ions
… in a trapezoidal prismatic topology and contains tetrazolate ligands that are formed via a metal-assisted click reaction. The molecular structure of the second {Ni18} cluster is highly disordered comprising of eight edge-sharing cubane subunits. Dc magnetic susceptibility measurements reveal …
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Use of Oximes and Schiff-bases as Bridging/Chelating Ligands with Select 3d and 3d/4f Ions in Cluster Chemistry and a Mechanistic Insight into the Roles of Transition Metal Ions in the Formation of Tetrazoles
… ZnII transition metal ions affording 5-methyl-tetrazolate (mtz-) heterocycles were computationally investigated via density functional theory (DFT). This is the first computational study to investigate the role of NiII in this cycloaddition reaction. Although a higher- and lower-level of theory …