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Showing 1 to 2 of 2 for “"Sulfenoamination"”.
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Lewis base catalyzed enantioselective sulfenoamination of alkenes
… successfully applied to the enantioselective sulfenoamination of olefins. The unreactive, achiral Lewis acidic sulfenylating agent, N-arylthiophthalimide, is activated by the coordination of a chiral Lewis base, binaphthyl-derived selenophosphoramide, in presence of a Brønsted acid as a …
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Stereoselective synthesis of 1,2-disubstitued βeta-amino alcohols and amino thiols
… catalytic, enantioselective, intermolecular, 1,2-sulfenoamination of alkenes. Functionalization is achieved through the intermediacy of an enantioenriched, configurationally stable thiiranium ion generated by Lewis base activation of a readily available sulfur electrophile. An expedited reaction …