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Showing 1 to 1 of 1 for “"Strecker Synthese"”.
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Zur asymmetrischen Synthese von Beta-Thio-Alpha-Aminosäuren
… (de = 43 - 61%). In a diastereoselctive Strecker-like reaktion the SAMP-hydrazones are transformed with TMSCN into the hydrazino nitriles (de = 90 - =<96%). Protection with Benzoylchloride and epimerisation free N,N-bound cleavage with SmI2 resulted the protected aminonitriles. Unhappily, …