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Showing 1 to 14 of 14 for “"Stereoisomerism"”.

  1. High-Nuclearity Lanthanide(III) Complexes as Single-Molecule Magnets and Luminescent Materials

    … Moreover, in order to investigate the steric and stereoisomerism effects of the ligand on the chemical and structural identity of the {Ln7} clusters, the pure trans-analogue of the sachH2 ligand was utilized. As a result, a new family of octanuclear [Ln8(OH)4(CO3)2(trans-sach)8(EtOH)4] (Ln = Gd …

    brock Repository record for High-Nuclearity Lanthanide(III) Complexes as Single-Molecule Magnets and Luminescent Materials (opens in a new tab)

  2. The Development of New Stereoselective Transformations Using Alkenyl Boronate Complexes

    Anionic, tetravalent alkenyl boron-"ate" complexes have emerged as powerful reagents for the stereoselective synthesis of chiral boronic esters via multicomponent coupling. These complexes can react with electrophiles through a 1,2-metalate rearrangement process, resulting in the net addition of a …

    utswmed Repository record for The Development of New Stereoselective Transformations Using Alkenyl Boronate Complexes (opens in a new tab)

  3. Iridium-Catalyzed Enantioselective Allylation of Alkenyl Boronates

    Organoboronic esters are highly functionalizable synthetic intermediates owing to their unique reactivity that allows for pre-complexation with organometallic reagents to form boronates, which can then engage in bimolecular reactions. Furthermore, incorporation of boronic esters into their …

    utswmed Repository record for Iridium-Catalyzed Enantioselective Allylation of Alkenyl Boronates (opens in a new tab)