Global ETD Search
Search theses and dissertations gathered from participating repositories worldwide. Every result links back to the library that holds it. No account is needed.
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Showing 1 to 4 of 4 for “"Solvation shells."”.
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Microsolvatación de cationes en disolución. Desarrollo del modelo de ion hidratado intercambiable y su aplicación a la química de cationes radiactivos
… complexes or aqua ions, defining different solvation shells which surround the central metal cation. This picture of the hydration structure was firstly proposed by Frank and Evans and is named as the concentric shells model 2 (see Fig. 1). In a global sense the formation of the aqua ion is …
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Physicochemical Study of Nano-structuring Within Ionic Liquids Using Photoswitchable Spirocyclic Compounds
… as it determines more complex processes such as solvation and reaction dynamics. It is believed that unique ordering in ionic liquids results form a balance between anion-cation, cation-cation and most importantly, ion-pair formation. The final parameter has been found to be critical to the …
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Understanding cation catalytic effects in electron transfer reactions at molecular scale
… up with the redox centers to modulate the local solvation characteristics, which in turn changes not only the reorganization energy but aslo the coupling between the redox centers. In Ch. 2, we quantified the indirect effects from the cations using various statis- tical tools. Moreover, we …
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Under confinement : molecular dynamics investigations of ions and molecules in nanopores and at nanoscale interfaces.
… energy penalties for ion entry. Ion density and solvation, along with the orientation of water molecules in charged and uncharged pristine nanotubes were also investigated. Carbon nanotubes having surface functionalization with hydrogen and hydroxyl groups were created to investigate the outcomes …