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Showing 1 to 20 of 31 for “"Solid state chemistry"”.
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Solid-State Chemistry of Benzophenone Anils (x-Ray, Crystallography)
… The strong preference for this isomer in the solid state is in sharp contrast to the behavior in solution where previous workers found that both isomers are present in nearly equal amounts at equilibrium.
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Structural studies of phosphinegold(I) thiolates with potential medicinal applications / by Douglas Robert Smyth.
… alkyl or ferrocene group. Demonstrates that the solid state chemistry of phosphinegold(I) thiolates remains difficult to predict when competing intra- and inter-molecular forces are present.
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Synergistic Properties-Driven Synthesis of Aluminides, Antiomonides, and Bioceramics
… is also reported. The demand of new inorganic solid materials as scaffolds for the engineering of bone tissue has led to the synthesis of calcium magnesium silicates such as, diopside (CaMgSi2O6), akermanite (Ca2MgSi2O7), monticellite (CaMgSiO4), and merwinite (Ca3Mg(SiO4)2)) for studying …
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Understanding the crystal landscape of primary sulfinamides and predicting cocrystallization
… an under-studied sulfur functional group from a solid state chemistry perspective. Their solid-state properties are examined, with focus on the robust supramolecular synthons that they exhibit. Finally, this chapter describes their hydrolysis, examining the relationship between their hydrolytic …
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LUMINESCENT 2D COORDINATION NETWORKS (CNS): STRUCTURAL AND EXFOLIATION STUDIES
… have emerged as a distinct subfield of the solid-state chemistry, aiming to develop and isolate layered networks with unique functionalities suitable for next-generation technologies. This research project focused on the synthesis and comprehensive characterization of novel 2D luminescent …
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Synthesis, structures, electronic structures and physical properties of quaternary alkali, alkaline earth, rare earth and transition metal pnictides
… and physical properties are still a challenge in solid-state chemistry. Based on the Zintl concepts, studing the crystal structures and electronic structures of Zintl phases, it provides a way to further understand and predict the physical properties of solid state materials. Therefore, we …
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Deracemizing Racemic Compounds
Contains fulltext : 143566.pdf (Publisher’s version ) (Open Access)
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Single chirality through crystal grinding
Contains fulltext : 74877.pdf (Publisher’s version ) (Open Access)
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Assessing Salt Hydrates For Thermochemical Heat Batteries
Contains fulltext : 299116.pdf (Publisher’s version ) (Open Access)
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Crystal structure and morphology prediction of organic pigments
Contains fulltext : 75422.pdf (Publisher’s version ) (Open Access)
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The preparation and characterisation of mixed-anion and non-oxide materials
Traditionally, research in solid-state chemistry has focused largely on the chemistry of oxides and on chemical tailoring of the structure and physical properties via cationic substitutions. Consequentially, the chemistry of non-oxide ompounds and other means of chemical tailoring, such as anionic …
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Calixarene and coordination complex hosts for anions.
… ligand binds with metal anions in solution and solid state chemistry. We synthesised simple pyridyl urea ligands and isomorphs. Their anion binding studies are discussed in terms of solid state and solution chemistry. Solid state structures based on silver and copper metal forming contact ion …
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Pharmaceutical analysis and in-vitro aerodynamic characterisation of inhaled theophylline formulations containing drug particles prepared by supercritical fluid processing. Chromatographic, spectroscopic, and thermal analysis of micron-sized theophylline particles prepared by supercritical fluid technology and in-vitro evaluation of their performance as inhaled dry powder formulations.
… by this method has been subject to a number of solid-phase analytical procedures designed to establish the crystal structure [X-ray powder diffraction (XRPD)], the structure and conformation [(FTIR), Fourier-transform Raman spectroscopy (FT-Raman)], and the morphology and particle size [scanning …
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Polar intermetallic compounds of the silicon and arsenic family elements and their ternary hydrides and fluorides
… on the effects of hydrogen and fluoride in the solid state chemistry of alkaline-earth and divalent rare-earth metal pnictide (Pn) and tetrelide (Tt) phases A5(Pn,Tt,)3Zx, where A = Ca, Sr, Ba, Sm, Eu, Yb; Pn = As, Sb, Bi; Tt = Si, Ge, Sn, Pb and Z = H, F. Several trivalent rare-earth-metal …
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Examination of stress-induced transformations within multicomponent pharmaceutical crystals
… strategies of design and synthesis of organic solids with the main focus being on improving the properties of the developed materials. Research in this area has a significant impact on large-scale manufacturing as industrial processes may give rise, at various stages, to stress-induced …
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Shock initiation of explosives under the microscope
… dissertation explores the shock compression of solid state explosives by thin, laser-driven flyer plates. These flyer plates consist of aluminum foils, typically 25 – 75 μm thick, which are launched using a Nd:YAG laser with a 20 ns pulse width in a technique developed within the Dlott group. A …
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Investigation of glucose hydrate formation and loss: Parameters, mechanisms, and physical stability
… deliquescence influenced by additional water-solid interactions, such as hydrate formation, under dynamic conditions. To enhance stability, GM is dried during production to a moisture content below its full stoichiometric monohydrate moisture content, and therefore hydrate formation is still …
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Navigating the Intermetallic Landscape: From Quasicrystal Approximants to High Pressure Crystal Chemistry
Building a comprehensive solid state chemical toolbox that pairs experimental studies and computational modeling has proven particularly effective for the systematic exploration of metal rich inorganic solids. Here, we explored the complex crystal chemistry enabled by incorporating Au in the …
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